Ionic EquilibriumHard

Question

On adding 0.1 M solution each of [Ag+], [Ba2+], [Ca2+] in a Na2So4 solution, species first precipited is

Options

A.Ag2So4
B.BaSo4
C.CaSo4
D.All of these

Solution

The species having minimum value of Ksp will get precipited first of all because ionic product will exceed the solubility product of such a species.
The Ksp value is minimum for BaSo4 (10-11), so BaSo4 will get precipited first of all.

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