Ionic EquilibriumHard

Question

Approximate pH of 0.1 M aqueous H2S solution when K1 and K2 for H2S at 25oC are 1 × 10-7 and 1.3 × 10-13 respectively :

Options

A.4
B.5
C.6
D.8

Solution

pH of 0.1 M H2S solution can be derived by :
    H2S  ⇋  H+ + HS- ; K1 = 1 × 10-7
∴  [H+] = Cα = C = 10-4
∴  pH = 4

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