Chemical BondingHard

Question

Given λm (in s cm2 mol-1) for Ca+2 = 119, Mg+2 = 106, Cl- = 76 and SO4-2 = 160 then calculate value of Λm for CaCl2 and MgSO4 respectively:-

Options

A.193.3 and 271.0 s cm2 mol-1
B.195 and 266 s cm2 mol-1
C.271 and 266 s cm2 mol-1
D.135.8 and 235.5 s cm2 mol-1

Solution

m) of CaCl2 = (Λm)Ca+2 + 2 (Λm)Cl-
= 119 + 2 × 76
= 119 + 152
= 271 s cm2 mol-1
m)MgSO4 = (Λm)Mg+2 + (Λm)SO4-2
= 106 + 160 = 266 s cm2 mol-1

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