Coordination CompoundHard

Question

Which of the following exhibit geometrical isomerism (M stands for a metal, and a and b are achiral ligands)?

Options

A.Ma2 b2
B.Ma2 b4
C.Ma5 b
D.Ma6

Solution

(A)  Ma2b2 :  - 2 (aa)(bb)            
                           (ab)(ab)            
(B) Ma2b4    -  2 (aa)(bb)(bb)        
                           (ab)(ab)(bb)        
(C) & (D) Ma5b and Ma6, have only one form. 

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