Coordination CompoundMediumBloom L3
Question
Ni(CO)4 and [Ni(NH3)4]2+ do not differ in
Options
A.magnetic moment
B.oxidation number of Ni
C.geometry
D.EAN
Solution
Sol. [Ni(CO)4]
Ni = 4s23d8 (CO → SFL)
→ sp3, tetrahedral, μ = 0 Bm
[Ni(NH3)4]+2 ⇒ Ni+2 = 3d8
(NH3 → SFL) ⇒ dsp2, (square planar)
⇒ μ = 0 Bm
Ni(CO)4 & [Ni(NH3)4]2+ do not differ in μ both have same magnetic moment
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