Ionic EquilibriumHard

Question

Choose the correct statement

Options

A.pH of acidic buffer solution decrease if more salt is added.
B.pH of acidic buffer solution increases if more salt is added.
C.pH of basic buffer decreases if more salt is added.
D.pH of basic buffer increases if more salt is added.

Solution

(B) is correct because pH = pKa + log for acidic buffer.
If [Salt] increases, pH of acidic buffer will increase.
pOH = pKb + log for basic buffer.
If [Salt] increases, pOH will increase, pH will decrease as pH = 14 - pOH.
Therefore (C) is correct but (D) is wrong.
(A) is not correct    pH = pKa + log
If [Salt] increase, pH will increase.

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