Chemical Kinetics and Nuclear ChemistryMedium

Question

If the half-life ( $t_{1/2}$ ) for a first order reaction is 1 minute, then the time required for $99.9\%$ completion of the reaction is closest to:

Options

A.2 minutes
B.4 minutes
C.5 minutes
D.10 minutes

Solution

Sol. [Key Concept: First-order reaction — time for 99.9% completion (≈10 half-lives)]

For $1^{\text{st}\text{~}}$ order reaction

$$\begin{matrix} & kt = 2.303log\frac{A_{0}}{A_{t}}A_{0} = \text{~}\text{initial concentration}\text{~} \\ & A_{t} = \text{~}\text{Final concentration}\text{~} \\ & t_{99.9\%} = 10t_{1/2} \\ & t_{99.9\%} = 10 \times 1\text{~}\text{minute}\text{~} = 10\text{~}\text{minutes}\text{~} \end{matrix}$$

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