Chemical Kinetics and Nuclear ChemistryHard
Question
For hypothetical reaction A → B takes place according to
$$A\overset{\quad K_{1}\quad}{\leftleftarrows}C\left( \text{fast} \right) $$$A + C\overset{\quad K_{2}\quad}{\rightarrow}B\left( \text{slow} \right)$
The rate of reaction is (K1 is equilibrium constant)
Options
A.K2[B][C]
B.K1K2[A]
C.K1K2[A]2
D.K1[B][C]
Solution
$r = K_{2}\lbrack A\rbrack\lbrack C\rbrack\text{ and }K_{1} = \frac{\lbrack C\rbrack}{\lbrack A\rbrack}$
$\therefore r = K_{1}K_{2}\lbrack A\rbrack^{2}$
Create a free account to view solution
View Solution FreeTopic: Chemical Kinetics and Nuclear Chemistry·Practice all Chemical Kinetics and Nuclear Chemistry questions
More Chemical Kinetics and Nuclear Chemistry Questions
A reaction which is of first order w.r.t reactant A, has a rate constant 6 min-1. If we start with [A] = 0.5 mol L-1, wh...In the following graphical representation for the reaction A → B there are two types of regions :...A certain reaction A → B follows the given concentration (Molarity)-time graph. Which of the following statements ...The bromination of acetone that occurs in acid solution is represented by CH3COCH3 (aq) + Br2 (aq) → CH3COCH2 Br (...For a given reaction, the concentration of the reactant plotted against time gave a straight line with negative slope. T...