ElectrochemistryHard

Question

From the following E° values for the half-cells:

(i) D → D2+ + 2e; E° = −1.5 V (ii) B+ + e → B; E° = − 0.5 V

(iii) A3− → A2− + e; E° = 1.5 V (iv) C2+ + e → C+; E° = +0.5 V

Which combination of two half-cells would result in a cell with largest potential?

Options

A.i and iii
B.i and iv
C.iii and iv
D.ii and iv

Solution

For (i) & (iii);$E_{cell}^{o} = 3.0\text{ V}$

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