Redox and Equivalent ConceptHard

Question

For a first order reaction A → P, the temperature (T) dependent rate constant (k) was found to follow the equation log k = - (2000) + 60. The pre-exponential factor A and the activation energy Ea, respectively, are

Options

A.1.0 × 106 s-1 and 9.2 kJmol-1
B.6.0 s-1 and 16.6 kJmol-1
C.1.0 × 106 s-1 and 16.6 kJmol-1
D.1.0 × 106 s-1 and 38.3 kJmol-1

Solution

Given, log K = 6 -
Since, log K = log A - So, A = 106 sec-1 and Ea = 38.3 kJ/mole

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