Atomic StructureHardBloom L3
Question
Consider an atom made up of a proton and a hypothetical particle that has double the mass of an electron but the same charge as the electron. Applying the Bohr atom model and considering all possible transitions of this hypothetical particle to the first excited state ($n = 2$), the longest wavelength photon emitted has wavelength $\lambda$ (expressed in terms of the Rydberg constant $R$ for hydrogen) equal to:
Options
A.$\dfrac{9}{5R}$
B.$\dfrac{36}{5R}$
C.$\dfrac{18}{5R}$
D.$\dfrac{4}{R}$
Solution
{"given":"A hypothetical atom with a proton and a particle of mass $m' = 2m_e$ (double the electron mass) and charge $-e$. The Rydberg constant for hydrogen is $R$. Find the longest wavelength photon emitted during transitions to the first excited state ($n = 2$).","key_observation":"In Bohr's model, the energy of the $n$th orbit scales linearly with the particle mass: $E_n \\propto m$. Doubling the mass doubles all energies, so the effective Rydberg constant becomes $R' = 2R$. The longest wavelength (minimum energy) transition to $n = 2$ is from $n = 3$.","option_analysis":[{"label":"(A)","text":"$\\dfrac{9}{5R}$","verdict":"incorrect","explanation":"This does not correspond to any valid transition in this hypothetical atom. The $n=3 \\to n=2$ transition gives $\\lambda = \\dfrac{18}{5R}$, not $\\dfrac{9}{5R}$."},{"label":"(B)","text":"$\\dfrac{36}{5R}$","verdict":"incorrect","explanation":"This would correspond to $R' = R$ (normal hydrogen), but here the effective Rydberg constant is $R' = 2R$, so this value is off by a factor of 2."},{"label":"(C)","text":"$\\dfrac{18}{5R}$","verdict":"correct","explanation":"With $R' = 2R$, the transition $n=3 \\to n=2$ gives $\\dfrac{1}{\\lambda} = 2R\\left(\\dfrac{1}{4} - \\dfrac{1}{9}\\right) = 2R \\cdot \\dfrac{5}{36} = \\dfrac{5R}{18}$, so $\\lambda = \\dfrac{18}{5R}$."},{"label":"(D)","text":"$\\dfrac{4}{R}$","verdict":"incorrect","explanation":"This value does not match the $n=3 \\to n=2$ transition with $R' = 2R$; it would require an unrealistic transition energy."}],"answer":"(C)","formula_steps":[]}
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