Ionic EquilibriumHard

Question

0.2 millimoles of Zn2+ ion is mixed with (NH4)2 S of molarity 0.02 M. The amount of Zn2+ remains unprecipitated in 20 mL of this solution would be (Given : KSP ZnS = 4 × 10-24)

Options

A.5.2 × 10-22 g
B.2.6 × 10-22 g
C.2 × 10-23 g
D.none of these

Solution

              S2-  +  Zn2+  →   ZnS (s)
m.moles  0.4        0.2
              0.2        -
so  in solution,
[S2-] = = 0.01 M
∴  [Zn2+] = = 4 × 10-22 M
∴  mass of Zn2+ remain unprecipitated in 20 ml of solution = × 20 × 65 = 5.2 × 10-22 gm.

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