Ionic EquilibriumHard

Question

When 0.1 mole solid NaOH is added in 1lt of 0.1M NH3(aq) then which statement is going to wrong?
(Kb = 2 × 10-5, log 2 = 0.3)

Options

A.degree of dissociation of NH3 approaches to zero.
B.change in pH would be 1.85
C.conc of [Na+] = 0.1M, [NH3] = 0.1M, [OH-] = 0.2M
D.on addition of OH-, Kb of NH3 does not changes.

Solution

Initial pOH     = (pKb - log C)  = (4.7 - log 0.1) = 2.85
Final pOH = 1
Change in pOH = Change in pH = 1.85

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