ElectrochemistryHard

Question

Using the data in the preceding problem, calculate the equilibrium constant of the reaction at 25oC.
Zn + Cu++ ⇋ Zn++ + Cu,  K =

Options

A.8.314 × 1024
B.4.831 × 1031
C.8.314 × 1036
D.4.831 × 1044

Solution

E298 = 1.1028 - 0.641 × 10-3 × 25 + 0.72 × 10-5 × (25)2 = 1.091275 Volt
= - 8.314 × 298 ln K = - 2 × 1.091275 × 96500
K = 1036.91= 8.128 × 1036.

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