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Question

Among the following, choose the ones with equal number of atoms.

A. 212 g of ${Na}_{2}{CO}_{3}(\text{ }s)$ [molar mass $= 106\text{ }g$ ]

B. 248 g of ${Na}_{2}O(s)$ [molar mass $= 62\text{ }g$ ]

C. 240 g of $NaOH(s)$ [molar mass $= 40\text{ }g$ ]

D. 12 g of $H_{2}(\text{ }g)$ [molar mass $= 2\text{ }g$ ]

E. 220 g of ${CO}_{2}(\text{ }g)$ [molar mass $= 44\text{ }g$ ]

Choose the correct answer from the options given below :

Options

A.A, B, and C only
B.A, B, and D only
C.B, C, and D only
D.B, D, and E only

Solution

Sol. [Key Concept: Equal number of atoms — mole concept calculation]

Number of atoms $= \frac{\text{~}\text{given mass}\text{~}}{\text{~}\text{molar mass}\text{~}} \times$ atomicity $\times N_{A}$

A. $\frac{212}{106} \times 6 \times N_{A} = 12{\text{ }N}_{A}$

B. $\frac{248}{62} \times 3 \times N_{A} = 12{\text{ }N}_{A}$

C. $\frac{240}{40} \times 3 \times N_{A} = 18\text{ }N\text{ }A$

D. $\ \frac{12}{2} \times N_{A} \times 2 = 12{\text{ }N}_{A}$

E. $\frac{220}{44} \times N_{A} \times 3 = 15\text{ }N\text{ }A$

$A,B$ and $D$ have same number of atoms

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