Chemical Kinetics and Nuclear ChemistryHard

Question

For the reactions of first, second and third orders, K1 = K2 = K3, where concentrations are expressed in ‘M’. The correct relation in K1, K2 and K3, if concentrations are expressed is mol ml−1 is

Options

A.K1 = K2 = K3
B.K1 × 10−3 = K2 = K3 × 103
C.K1 = K2 × 10−3 = K3 × 10−6
D.K1 × 103 = K2 × 10−3 = K3

Solution

K1(Ms–1) = K2 (s–1) = K3(M–1 s–1)

or, K1 × 10–3 (mol ml–1 s–1) = K2 (s–1) = K3 × 10–3 (mol ml–1 s–1)

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