ElectrochemistryHard
Question
Calculate $\Lambda_{m}^{\infty}$ (in Ω−1 cm2 mol−1) for SrCl2 at 25°C, from the following data:
Conc. 0.25 M 1.0 M
Λm (in Ω−1 cm2 mol−1) 260 250
Options
A.270
B.265
C.240
D.275
Solution
$\Lambda_{m} = \Lambda_{m}^{o} - A\sqrt{C}\left( \text{for strong electrolyte} \right)$
$\text{Or, 260 = }\Lambda_{m}^{o} - A \times \sqrt{0.25}(1) $$${250 = \Lambda_{m}^{o} - A \times \sqrt{1.00}(2) }{\therefore\Lambda_{m}^{o} = 270\text{ oh}\text{m}^{- 1}\text{ c}\text{m}^{2}\text{ mo}\text{l}^{- 1}}$$
Create a free account to view solution
View Solution FreeMore Electrochemistry Questions
The following galvanic cell: Zn|Zn(NO3)2 (100 ml, 1 M)||Cu(NO3)2 (100 ml, 1 M)|Cu was operated as an electrolytic cell a...The oxidation potentials of Zn, Cu, Ag, H2 and Ni are 0.76, -0.34, -0.80, 0.00, 0.25 volt, respectively. Which of the fo...From an electrolyte, one mole of electron will deposit at cathode...What is the amount of chlorine evolved, when 2 amp of current is passed for 30 minutes in an aqueous solution of NaCl?...In the balanced chemical reaction, IO3- + aI- + bH+ → cH2O + dI2 a, b, c and d respectively to...