ElectrochemistryHard
Question
Calculate $\Lambda_{m}^{\infty}$ (in Ω−1 cm2 mol−1) for SrCl2 at 25°C, from the following data:
Conc. 0.25 M 1.0 M
Λm (in Ω−1 cm2 mol−1) 260 250
Options
A.270
B.265
C.240
D.275
Solution
$\Lambda_{m} = \Lambda_{m}^{o} - A\sqrt{C}\left( \text{for strong electrolyte} \right)$
$\text{Or, 260 = }\Lambda_{m}^{o} - A \times \sqrt{0.25}(1) $$${250 = \Lambda_{m}^{o} - A \times \sqrt{1.00}(2) }{\therefore\Lambda_{m}^{o} = 270\text{ oh}\text{m}^{- 1}\text{ c}\text{m}^{2}\text{ mo}\text{l}^{- 1}}$$
Create a free account to view solution
View Solution FreeMore Electrochemistry Questions
The cell Pt (H2) (1 atm) | (pH = ?) || (a = 1) | AgI(s), Ag has emf, E298K = 0. The standard electrode potential for the...The standard oxidation potentials, Eo, for the half reactions are asZn → Zn2+ + 2e- ; Eo = + 0.76 V → Fe ...Perdisulphuric acid, H2S2O8 can be prepared by electrolytic oxidation of H2SO4, oxygen and hydrogen gases are by product...What would be the magnitude of the EMF of the following cell:Pt(H2) =Pt(H2) at 25oC ? The ionization constant of acetic ...If the cell reaction is spontaneous then...