SolutionHard
Question
At 100°C, the vapour pressure of a solution of 4.0 g of solute in 100 g of water is 750 mm. The boiling point of the solution is (kb of water = 0.52 K-kg/mol)
Options
A.100°C
B.100.04°C
C.100.4°C
D.104.0°C
Solution
If molality of solution is ‘m’, then
$\frac{P^{o} - P}{P} = \frac{n_{1}}{n_{2}} \Rightarrow \frac{760 - 750}{750} = \frac{m}{1000/18} \Rightarrow m = \frac{20}{27}$
Now, $\Delta T_{b} = K_{b}.m = 0.52 \times \frac{20}{27} = 0.358\text{ K}$
∴ B.P. of solution = 100.385° C
Create a free account to view solution
View Solution FreeMore Solution Questions
Azeotropic mixture of liquids can only be separated by...The solubility of Al(OH)3 and Zn(OH)2 are and 1.8 × 10-14, respectively. If NH4OH is added to a solution containing...Depression of freezing point of 0.01 molal aq. CH3COOH solution is 0.02046o. 1 molal urea solution freezes at - 1.86°C. ...One molal solution of benzoic acid in benzene boils at 81.53°C. The normal boiling point of benzene is 80.10°C. Assuming...Which of the following has been arranged in order of decreasing freezing point?...