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Question
Aqueous solutions of 0.004 M-Na2SO4 and 0.01 M-Glucose are isotonic. The percentage dissociation of Na2SO4 is
Options
A.25%
B.60%
C.75%
D.40%
Solution
$\underset{0.004(1 - \alpha)M}{Na_{2}SO_{4}} \rightleftharpoons \underset{0.004 \times 2\alpha}{2Na^{+}} + \underset{0.004 \times \alpha}{SO_{4}^{2 -}}$
Effective molarity = 0.004(1 – α) + 0.008α + 0.004α = 0.004 + 0.008α
For solution to be isotonic,
0.004 + 0.008α = 0.01 ⇒ α = 0.75
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