NEET | 2017Chemical BondingHard

Question

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexs : CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is :-

Options

A.

3 AgCl, 1 AgCl, 2 AgCl

B.

3 AgCl, 2 AgCl, 1 AgCl

C.

2 AgCl, 3 AgCl, 1 AgCl

D.

1 AgCl, 3 AgCl, 2 AgCl

Solution

[CO(NH3)6]Cl3  →AgNO3  3 mol AgCl
[CO(NH3)5 Cl]Cl2 →AgNO3 2 mol AgCl
[CO(NH3)4 Cl2]Cl →AgNO3 1 mol AgCl

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