JEE Advanced | 2017Atomic StructureHard

Question

Among the following, the correct statement(s) is(are)

Options

A.

Al(CH3)3 has the three-centre two-electron bonds in its dimeric structure

B.

BH3 has the three-centre two-electron bonds in its dimeric structure

C.

AlCl3 has the three-centre two-electron bonds in its dimeric structure

D.

The Lewis acidity of BCl3 is greater than that of AlCl3

Solution

Both Al(CH3)3 and BH3 has 3c – 2e bonds in the dimeric structure.

BCl3 is stronger Lewis acid than AlCl3.

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