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Question

The molar heat capacity at constant presure of nitrogen gas at STP is nearly 3.5 R. Now when  the temperature is increased, it gradually increases and approaches 4.5 R. The most appropriate reason for this behaviour is that at high temperatures    

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A.The molar heat capacity at constant presure of nitrogen gas at STP is nearly 3.5 R. Now when  the temperature is increased, it gradually increases and approaches 4.5 R. The most appropriate reason for this behaviour is that at high temperatures    
B.nitrogen molecules dissociate in atoms
C.the molecules collides more frequently    
D.molecular vibration gradually become effective

Solution

(D)
CP =  3.5 R  (At STP)
As temperature increases, vibrational degree of freedom becomes 2 at higher temperature.
CP = 8/2 R = 4.5 R

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