Mole ConceptHard

Question

When burnt in air, a 12.0 g mixture of carbon and sulphur yields a mixture of CO2 and SO2, in which the number of moles of SO2 is half that of CO2. The mass of the carbon the mixture contains is (At. wt. S = 32)

Options

A.4.08 g
B.5.14 g
C.8.74 g
D.1.54 g

Solution

Let mass of C = X gm
                  C    +  O2  → CO2
Initial mole            -             0
final mole     0                      2a
                  S      +    O2 → SO2
Initial mole           -           0
final mole     0          -                    a
Mole of C = Mole of CO2
= 2a
Mole of S = Mole of SO2
= a
∴  = 2
x = (12 - x)
4x = 36 - 3x
x = = 5.14 gm

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