Chemical EquilibriumHard

Question

The degree of dissociation of PCl5 (a) obeying the equilibrium, PCl5 ⇋ PCl3 + Cl2, is approximately related to the presure at equilibrium by (given α << 1) :

Options

A.α ∝ P
B.α ∝ 1√P
C.α ∝ 1√P2
D.α ∝ 1√P4

Solution

KP = P ≈ α2P.
so       α ≈

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