Coordination CompoundHard
Question
Which of the following complexes shows ionization isomerism ?
Options
A.[Cr(NH3)6]Cl3
B.[Cr(en)2]Cl2
C.[Cr(en)3]Cl3
D.[Co(NH3)5Br]SO4
Solution
(A) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(B) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(C) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(D) Br- and SO4- can exchange their positions between coordination sphere and ionisation sphere. Hence it shows ionization isomerism.
(B) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(C) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(D) Br- and SO4- can exchange their positions between coordination sphere and ionisation sphere. Hence it shows ionization isomerism.
Create a free account to view solution
View Solution FreeMore Coordination Compound Questions
Which of the following statement(s) is/are correct ?...The purple colour of KMnO4 is due to the transition...All the metal ions contains t2g 6eg0 configurations. Which of the following complex will be paramagnetic?...Which of the following does not have optical isomer?...Which of the following statements is correct for complex [Cr(NH3)(CN)4(NO)]2 - (given that n = 1)?...