Coordination CompoundHard
Question
Which of the following complexes shows ionization isomerism ?
Options
A.[Cr(NH3)6]Cl3
B.[Cr(en)2]Cl2
C.[Cr(en)3]Cl3
D.[Co(NH3)5Br]SO4
Solution
(A) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(B) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(C) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(D) Br- and SO4- can exchange their positions between coordination sphere and ionisation sphere. Hence it shows ionization isomerism.
(B) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(C) No anionic ligand is present in coordination sphere for the exchange with Cl- ions present in ionisation sphere.
(D) Br- and SO4- can exchange their positions between coordination sphere and ionisation sphere. Hence it shows ionization isomerism.
Create a free account to view solution
View Solution FreeMore Coordination Compound Questions
In which of the following pairs both the copmplexes show optical isomerism?...The correct increasing order of spin-only magnetic moment values of the complex ions$\left\lbrack {MnBr}_{4} \right\rbra...Tetrahedral complexes are generally favoured :...Which of the following complexes is correctly matched with their geometries ?...Consider the transition metal ions ${Mn}^{3 +},{Cr}^{3 +},{Fe}^{3 +}$ and ${Co}^{3 +}$ and all form low spin octahedral ...