Coordination CompoundHard

Question

Complex ion [ FeN3(O2)(SCN)4]4 - is named as : (coordination number of central metal ion in complex is six)

Options

A.azidosuperoxidotetrathiocyanato-S-ferrate(II)
B.azidodioxygentetrathiocyanatoferrate(III)
C.azidoperoxidotetrathiocyanato-S-ferrate(II)
D.azidodioxidotetrathiocyanato-S-ferrate(III)

Solution

[Fe(II)N3-1(O2-1)(SC N)4-4]4-. ; so correct name is azidosuperoxidotetrathiocyanato-S-ferrate(II) according to IUPAC rules.

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