Ionic EquilibriumHard

Question

100 ml of 0.5M hydrazoic acid (HN3, Ka = 3.6 × 10-4) and 400ml of 0.1M cyanic acid (HOCN, Ka = 8 × 10-4) are mixed. which of the following is (are) true for the final solution?

Options

A.[H+] = 10-2 M
B.[N3-] = 3.6 × 10-3 M
C.[OCN-] = 6.4 × 10-3 M
D.[H+] = 1.4 × 10-2 M

Solution

Total [H+] =
∴  [H+] = 10-2 M.
For HN3,  [N3-] = × 100 = 3.6 × 10-3 M.
For HOCN,  [OCN-] = = 6.4 × 10-3 M.

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