Ionic EquilibriumHard

Question

Which of the following statements is correct for a solution saturated with AgCl and AgBr if their solubilities in moles per litre in separate solutions are x and y respectively ?

Options

A.[Ag+] = x + y
B.[Ag+] = [Br-] + [Cl-]
C.[Br-] = y
D.[Cl-] > x.

Solution

AgCI ⇋ Ag+  +  CI-         AgBr  ⇋  Ag+   +   Br-
                x          x                         y           y
           (x + y)       x                    (x + y)        y
So      [Ag+]  =  [Br-] + [CI–]

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