Ionic EquilibriumHard

Question

Which of the following statements are true for a solution saturated with AgCI and AgBr if their solubilities in mol per litre in separate solution are x and y mole respectively:

Options

A.[Ag+] = [Br-] × [CI-]
B.[CI-] > [Br]
C.[Br-] > y
D.[Ag+] = x + y

Solution

AgCI  ⇋  Ag+  + CI- ; AgBr ⇋  Ag+  + Br-
                      x       x                                   y        y
In simultaneous solubility solution  contains [Ag+] = [CI-] + [Br-]

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