Chemical Kinetics and Nuclear ChemistryHard
Question
For the complex Ag+ + 2NH3 ⇋ [Ag(NH3)2+]
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]
Hence, ratio of rate constants of the forward and backward reactions is :
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]Hence, ratio of rate constants of the forward and backward reactions is :
Options
A.2 × 107 L2 mol-2
B.2 × 109 L2 mol-2
C.1 × 10-2 L2 mol-2
D.0.5 × 10-9 L2 mol-2
Solution
Equation : Ag+ + 2NH3 ⇋ [Ag(NH3)2+]
Given,
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]
For equilibrium
= 0
2 × 107 [Ag+] [NH3]2 -1 × 10-2 [Ag(NH3)2+] = 0
= 2 × 109 L2 mol-2.
Given,
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]For equilibrium
= 0 2 × 107 [Ag+] [NH3]2 -1 × 10-2 [Ag(NH3)2+] = 0
= 2 × 109 L2 mol-2. Create a free account to view solution
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