Chemical Kinetics and Nuclear ChemistryHard
Question
For the complex Ag+ + 2NH3 ⇋ [Ag(NH3)2+]
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]
Hence, ratio of rate constants of the forward and backward reactions is :
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]Hence, ratio of rate constants of the forward and backward reactions is :
Options
A.2 × 107 L2 mol-2
B.2 × 109 L2 mol-2
C.1 × 10-2 L2 mol-2
D.0.5 × 10-9 L2 mol-2
Solution
Equation : Ag+ + 2NH3 ⇋ [Ag(NH3)2+]
Given,
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]
For equilibrium
= 0
2 × 107 [Ag+] [NH3]2 -1 × 10-2 [Ag(NH3)2+] = 0
= 2 × 109 L2 mol-2.
Given,
= 2 × 107 L2 mol-2 s-1 [Ag+] [NH3]2 - 1 × 10-2 s-1 [Ag(NH3)2+]For equilibrium
= 0 2 × 107 [Ag+] [NH3]2 -1 × 10-2 [Ag(NH3)2+] = 0
= 2 × 109 L2 mol-2. Create a free account to view solution
View Solution FreeTopic: Chemical Kinetics and Nuclear Chemistry·Practice all Chemical Kinetics and Nuclear Chemistry questions
More Chemical Kinetics and Nuclear Chemistry Questions
An organic compound undergoes first order decomposition. The time taken for decomposition to $\left( \frac{1}{8} \right)...Incorrect order of stablility is :...For a second order reaction plots are made for vs time for the reaction, 2A → Product. Pick up the correct sentenc...Penetrating power of α-particle is :...What is the activation energy for a reaction if its rate doubles when the temperature is raised from 20oC to 35oC ? (R =...