Atomic StructureHard

Question

A metal oxide has the formula Z2O3. It can be reduced by hydrogen to give free metal and water. 0.2 g of the metal oxide requires 12 mg of hydrogen for complete reduction. The atomic weight of the metal is

Options

A.52
B.104
C.26
D.78

Solution

Z2O3  + 3H2 →   2z + 3H2O
[0.2 g = 200 mg]          
      = 6 m mol
Since H2 used is 6 m mol, Z2O3 used should be 2 m mol.
Mol of Z2O3 = = 2 × 10-3 moles
∴ Mw(Z2O3) = 100
∴ 2z + 16 × 3 = 100
z = = 26

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