Chemical BondingMedium

Question

Match List I with List II.

List I (Compound) List II(Shape/geometry)
A. ${NH}_{3}$ I. Trigonal Pyramidal
B. ${BrF}_{5}$ II. Square Planar
C. ${XeF}_{4}$ III. Octahedral
D. ${SF}_{6}$ IV. Square Pyramidal

Choose the correct answer from the options given below:

Options

A.A-III, B-IV, C-I, D-II
B.A-II, B-III, C-IV, D-I
C.A-I, B-IV, C-II, D-III
D.A-II, B-IV, C-III, D-I

Solution

Sol. [Key Concept: Molecular shapes from VSEPR]

${NH}_{3} \Rightarrow sp^{3}$ hybridised with 1 lone pair. Structure will be Trigonal Pyramidal.

${BrF}_{5} \Rightarrow sp^{3}d^{2}$ hybridised with 1 lone pair. Structure will be Square Pyramidal.

${XeF}_{4} \Rightarrow sp^{3}d^{2}$ with two lone pairs. Structure will be Square Planar.

$SF_{6} \Rightarrow sp^{3}d^{2}$ with no lone pair. Structure will be Octahedral.

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