Chemical BondingMedium

Question

The highest occupied molecular orbital for ${Ne}_{2}$ is

Options

A.$\pi_{2p}^{*}$
B.$\sigma_{2p}^{*}$
C.$\ \pi_{2p}$
D.$\sigma_{2p}$

Solution

Sol. [Key Concept: MO theory — Ne₂ HOMO and zero bond order]

${Ne}_{2}:\sigma 1{\text{ }s}^{2} < \sigma^{*}1{\text{ }s}^{2} < \sigma 2{\text{ }s}^{2} < \sigma^{*}2{\text{ }s}^{2} < \sigma 2p_{z}^{2} < \left( \pi 2p_{x}^{2} = \pi 2p_{y}^{2} \right) < \pi^{*}2p_{x}^{2} = \pi^{*}2p_{y}^{2} < \sigma^{*}2p_{z}^{2}$ $\sigma^{*}2p_{z}$ i.e. $\sigma^{*}2p$ is highest occupied orbital.

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