Chemical BondingMedium

Question

Match the species in List-I with their geometry in List-II.

List-I List-II
A. $${PCl}_{5}$$ I. Tetrahedral
B. $${BrF}_{5}$$ II. Square Planar
C. $${BF}_{4}^{-}$$ III. Trigonal bipyramidal
D. $$\left\lbrack Ni(CN)_{4} \right\rbrack^{2 -}$$ IV. Square pyramidal

Choose the correct answer from the options given below:

Options

A.A-III, B-I, C-II, D-IV
B.A-III, B-II, C-I, D-IV
C.A-IV, B-III, C-I, D-II
D.A-III, B-IV, C-I, D-II

Solution

Sol. [Key Concept: VSEPR — molecular geometry]

Compound Hybridization of central atom/ion Geometry
A. $${PCl}_{5}$$ $${sp}^{3}\text{ }d$$ Trigonal bipyramidal
B. $${BrF}_{5}$$ $${sp}^{3}{\text{ }d}^{2}$$ Square pyramidal
C. $${BF}_{4}^{-}$$ $${sp}^{3}$$ Tetrahedral
D. $$\left\lbrack Ni(CN)_{4} \right\rbrack^{2 -}$$ $${dsp}^{2}$$ Square planar

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