Chemical BondingMedium
Question
Match the species in List-I with their geometry in List-II.
| List-I | List-II | ||
|---|---|---|---|
| A. | $${PCl}_{5}$$ | I. | Tetrahedral |
| B. | $${BrF}_{5}$$ | II. | Square Planar |
| C. | $${BF}_{4}^{-}$$ | III. | Trigonal bipyramidal |
| D. | $$\left\lbrack Ni(CN)_{4} \right\rbrack^{2 -}$$ | IV. | Square pyramidal |
Choose the correct answer from the options given below:
Options
A.A-III, B-I, C-II, D-IV
B.A-III, B-II, C-I, D-IV
C.A-IV, B-III, C-I, D-II
D.A-III, B-IV, C-I, D-II
Solution
Sol. [Key Concept: VSEPR — molecular geometry]
| Compound | Hybridization of central atom/ion | Geometry | |
|---|---|---|---|
| A. | $${PCl}_{5}$$ | $${sp}^{3}\text{ }d$$ | Trigonal bipyramidal |
| B. | $${BrF}_{5}$$ | $${sp}^{3}{\text{ }d}^{2}$$ | Square pyramidal |
| C. | $${BF}_{4}^{-}$$ | $${sp}^{3}$$ | Tetrahedral |
| D. | $$\left\lbrack Ni(CN)_{4} \right\rbrack^{2 -}$$ | $${dsp}^{2}$$ | Square planar |
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