ElectrochemistryMedium
Question
A solution of copper sulphate is electrolyzed for 10 minutes with a current of 1.5 amperes. The mass of copper deposited at cathode is:
(Given: Molar mass of $Cu = 63\text{ }g{\text{ }mol}^{- 1}$;
$1\text{ }F = 96487C{mol}^{- 1}$ )
Options
A.1.7018 g
B.0.2938 g
C.2.4036 g
D.0.5876 g
Solution
Sol. [Key Concept: Faraday's laws of electrolysis: m = (E·I·t)/F]
${CuSO}_{4} \longrightarrow {Cu}^{2 +} + {SO}_{4}^{2 -}$
$$\begin{matrix} 2e^{-} & \ + {Cu}^{2 +} \longrightarrow Cu(\text{ }s) \\ W & \ = zit \\ & \ = \frac{E \times it}{96500} \\ & \ = \frac{63 \times 1.5 \times 10 \times 60}{2 \times 96500} \\ & \ = \frac{56,700}{193000} = 0.2938\text{ }g \end{matrix}$$
Create a free account to view solution
View Solution FreeMore Electrochemistry Questions
The correct cell diagram for the following reaction and Eo for the cell is2AgBr(s) + H2(g) → 2Ag(s) + 2H+ + 2Br−; $E_{Ag...When molten ICI3 is electrolysed using platinum electrodes...Which of the following has longest C - O bond :...The standard EMF of a Daniel cell at 298 K is E1. When the concentration of ZnSO4 is 1.0 M and that of CuSO4 is 0.01 M, ...What is cell entropy change of the following cell ?Pt(s) | H2 (g) | CH3COOH, HCl || KCl (aq) | Hg2Cl2 (s) | Hg P = 1 atm...