ElectrochemistryMedium

Question

A solution of copper sulphate is electrolyzed for 10 minutes with a current of 1.5 amperes. The mass of copper deposited at cathode is:

(Given: Molar mass of $Cu = 63\text{ }g{\text{ }mol}^{- 1}$;

$1\text{ }F = 96487C{mol}^{- 1}$ )

Options

A.1.7018 g
B.0.2938 g
C.2.4036 g
D.0.5876 g

Solution

Sol. [Key Concept: Faraday's laws of electrolysis: m = (E·I·t)/F]

${CuSO}_{4} \longrightarrow {Cu}^{2 +} + {SO}_{4}^{2 -}$

$$\begin{matrix} 2e^{-} & \ + {Cu}^{2 +} \longrightarrow Cu(\text{ }s) \\ W & \ = zit \\ & \ = \frac{E \times it}{96500} \\ & \ = \frac{63 \times 1.5 \times 10 \times 60}{2 \times 96500} \\ & \ = \frac{56,700}{193000} = 0.2938\text{ }g \end{matrix}$$

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