Coordination CompoundMedium

Question

Match List I with List II:

List-I (Complex) List-II (Type of isomerism)
A. $$\left\lbrack Pt\left( {NH}_{3} \right)_{2}{Cl}_{2} \right\rbrack$$ I. Optical
B. $$\left\lbrack Co(en)_{3} \right\rbrack^{3 +}$$ II. Solvate
C. $$\left\lbrack Co\left( {NH}_{3} \right)_{5}{NO}_{2} \right\rbrack{Cl}_{2}$$ III. Geometrical
D. $$\left\lbrack Cr\left( H_{2}O \right)_{6} \right\rbrack{Cl}_{3}$$ IV. Linkage

Choose the correct Ans. from the options given below:

Options

A.A-III, B-I, C-II, D-IV
B.A-I, B-III, C-II, D-IV
C.A-II, B-IV, C-III, D-I
D.A-III, B-I, C-IV, D-II

Solution

Sol. [Key Concept: Matching compounds with characteristic tests]

A.

B.

C. $\left\lbrack Co\left( {NH}_{3} \right)_{5}{NO}_{2} \right\rbrack{Cl}_{2}$ and $\left\lbrack Co\left( {NH}_{3} \right)_{5}(ONO) \right\rbrack{Cl}_{2}$ are linkage isomers

D. $\ \left\lbrack Cr\left( H_{2}O \right)_{6} \right\rbrack{Cl}_{3}$ and $\left\lbrack Cr\left( H_{2}O \right)_{5}Cl \right\rbrack{Cl}_{2} \cdot H_{2}O$ are solvate isomers

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