Alkyl Halides and Aryl HalidesMedium

Question

n-Butane on monochlorination under photochemical conditions gives an optically active compound "P". "P" on further chlorination gives dichloro compounds.

The number of dichloro compounds obtained (ignore stereoisomers) is :

Options

A.3
B.4
C.5
D.6

Solution

Sol. [Key Concept: $n$-butane monochlorination gives optically active $2$-chlorobutane (P); further chlorination of P yields $4$ dichloro constitutional isomers (ignoring stereoisomers).]

Total dichloro products (excluding stereoisomers) = 4

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