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Question

Match List-I with List-II.

List-I
Electronic configuration of neutral atom (where
$\mathbf{n = 2}$ )

List-II

$\mathbf{1}^{\text{st}\text{~}}$ Ionization
Energy (
${\mathbf{kJ}\text{ }\mathbf{mol}}^{\mathbf{- 1}}$ )

A. ${ns}^{2}$ I. 2080
B. $ns^{2}np^{1}$ II. 899
C. $ns^{2}np^{3}$ III. 800
D. $ns^{2}np^{6}$ IV. 1402

List-II

$\mathbf{1}^{\text{st}\text{~}}$ Ionization

Energy ( ${\mathbf{kJ}\text{ }\mathbf{mol}}^{\mathbf{- 1}}$ )

Choose the correct answer from the options given below:

Options

A.A-II, B-III, C-IV, D-I
B.A-IV, B-III, C-II, D-I
C.A-III, B-II, C-IV, D-I
D.A-III, B-II, C-I, D-IV

Solution

Sol. [Key Concept: Match ${ns}^{2}$ (Be, $899$), ${ns}^{2}{np}^{1}$ (B, $800$), ${ns}^{2}{np}^{3}$ (N, $1402$) and ${ns}^{2}{np}^{6}$ (Ne, $2080$): the IE order $B < Be < N < Ne$ gives A-II, B-III, C-IV, D-I.]

(A) $2{\text{ }s}^{2} \Rightarrow Be$

(B) $2{\text{ }s}^{2}2p^{1} \Rightarrow \text{ }B$

(C) $2s^{2}2p^{3} \Rightarrow \text{ }N$

(D) $2{\text{ }s}^{2}2p^{6} \Rightarrow Ne$

IE order : $B < Be < N < Ne$

A-II, B-III, C-IV, D-I

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