Periodic TableHard

Question

Given below are two statements:

Statement-I: The correct order in terms of atomic/ionic radii is $Al > Mg > {Mg}^{2 +} > {Al}^{3 +}$.

Statement-II: The correct order in terms of the magnitude of electron gain enthalpy is $Cl > Br > S > O$.

In the light of the above statements, choose the correct answer from the options given below:

Options

A.Both Statement I and Statement II are false
B.Statement I is false but Statement II is true
C.Statement I is true but Statement II is false
D.Both Statement I and Statement II are true

Solution

Correct order of size is $Mg > Al > {Mg}^{2 +} > {Al}^{3 +}$

Atomic size depends mainly upon $Z_{\text{effective~}}$ and shell number.

Generally on moving down the group electron affinity decreases and on moving across the period electron affinity increase.

In the periodic table Cl has maximum electron affinity. Halogen has higher electron affinity than Chalcogen.

$$Cl > Br > S > O $$

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