Chemical BondingMedium

Question

Given below are two statements:

Statement I: $F_{2}O < H_{2}O < {Cl}_{2}O$ is the correct trend in terms of bond angle.

Statement II : ${SiF}_{4},{SnF}_{4}$ and ${PbF}_{4}$ are ionic in nature.

In the light of the above statements, choose the correct answer from the options given below :

Options

A.Both Statement I and Statement II are true
B.Both Statement I and Statement II are false
C.Statement I is true but Statement II is false
D.Statement I is false but Statement II is true

Solution

Sol. [Key Concept: Bond angle order $F_{2}O < H_{2}O < {Cl}_{2}O$ is correct (Statement I true), but ${SiF}_{4},{SnF}_{4},{PbF}_{4}$ are covalent, not ionic (Statement II false).]

$${OCl}_{2}$$ $$111^{\circ}$$
$$H_{2}O$$ $${104.5}^{\circ}$$
$${OF}_{2}$$ $$103^{\circ}$$

${SiF}_{4}$ is covalent.

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