General Organic ChemistryMedium

Question

The descending order of acidity among the following compounds is

A.

B.

C.

D.

E.

Choose the correct answer from the option given below options

Options

A.B $>$ D $>$ E $>$ A $>$ C
B.D $>$ B $>$ E $>$ A $>$ C
C.C $>$ A $>$ B $>$ D $>$ E
D.D $>$ E $>$ B $>$ A $>$ C

Solution

Sol. [Key Concept: Rank by electron-withdrawing power: carboxylic acids beat phenols and $- {NO}_{2}$ raises acidity, giving the order D $>$ E $>$ B $>$ A $>$ C.]

Theory based. Benzoic acid is more acidic than phenol. Electron withdrawing group in increases acidicity.

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