Alcohol, Phenol and EtherMedium

Question

Match List-I with List-II.

List-1

Mixture of Compounds

List=II

Reagent used to distinguish

A Diethyl amine + Ethyl amine I Bromine water
B Acetaldehyde + Acetone II $${CHCl}_{3} + KOH,\Delta $$
C Ethanol + Phenol III Neutral ${FeCl}_{3}$
D Benzoic acid + Cinnamic acid IV Ammonical silver nitrate

List-1

Mixture of Compounds

List=II

Reagent used to distinguish

Choose the correct answer from the options given below :

Options

A.A-IV, B-II, C-I, D-III
B.A-IV, B-II, C-III, D-I
C.A-II, B-IV, C-I, D-III
D.A-II, B-IV, C-III, D-I

Solution

Sol. [Key Concept: Match each pair to its distinguishing test (neutral FeCl3, carbylamine, Tollens', bromine water).]

- Phenol gives violet colour with neutral ${FeCl}_{3}$ not ethanol.

$1^{\circ}$ amine gives positive test with ${CHCl}_{3}/KOH$ not $2^{\circ}$ amine.

Aldehyde gives positive test with ammonical silver nitrate not ketone.

Cinnamic acid gives bromine water test.

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