Coordination CompoundHardBloom L3

Question

Of the following which is diamagnetic in nature?

Options

A.[CoF6]3–
B.[NiCl4]2–
C.[CuCl4]2–
D.[Ni(CN)4]2–

Solution

Sol. [Ni(CN)4]–2

⇒ Ni+2 = 3d8

⇒ dsp2 ⇒ square planar

⇒ diamagnetic.

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