p-Block elementsHardBloom L3
Question
H3BO3 $\overset{\quad T_{1}\quad}{\rightarrow}$ X $\overset{\quad T_{2}\quad}{\rightarrow}$ Y $\overset{\quad redhot\quad}{\rightarrow}$ B2O3
If T1 < T2 then X and Y respectively are
Options
A.X = Metaboric acid and Y = Tetraboric acid
B.X = Tetraboric acid and Y = Metaboric acid
C.X = Borax and Y = Metaboric acid
D.X = Tetraboric acid and Y = Borax
Solution
Sol. K4[Fe(CN)6] when heated with concenterated H2SO4 gives CO.
K4[Fe(CN)6]+6H2SO4+6H2O→2K2SO4+FeSO4+3(NH4)2SO4+6CO
When reacted with boiling dilute H2SO4 it gives HCN.
2K4[Fe(CN)6]+3H2SO4→3K2SO4+K2Fe[Fe(CN)6]+6HCN
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