p-Block elementsHardBloom L3

Question

H3BO3 $\overset{\quad T_{1}\quad}{\rightarrow}$ X $\overset{\quad T_{2}\quad}{\rightarrow}$ Y $\overset{\quad redhot\quad}{\rightarrow}$ B2O3

If T1 < T2 then X and Y respectively are

Options

A.X = Metaboric acid and Y = Tetraboric acid
B.X = Tetraboric acid and Y = Metaboric acid
C.X = Borax and Y = Metaboric acid
D.X = Tetraboric acid and Y = Borax

Solution

Sol. K4​[Fe(CN)6​] when heated with concenterated H2​SO4​ gives CO.

K4​[Fe(CN)6​]+6H2​SO4​+6H2​O→2K2​SO4​+FeSO4​+3(NH4​)2​SO4​+6CO

When reacted with boiling dilute H2​SO4​ it gives HCN.

2K4​[Fe(CN)6​]+3H2​SO4​→3K2​SO4​+K2​Fe[Fe(CN)6​]+6HCN

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