ThermodynamicsHard

Question

$20.0{dm}^{3}$ of an ideal gas ' X ' at 600 K and 0.5 MPa undergoes isothermal reversible expansion until pressure of the gas is 0.2 MPa . Which of the following option is correct?

(Given: $log2 = 0.3010$ and $log5 = 0.6989$ )

Options

A.$w = - 9.1\text{ }kJ,\Delta U = 0,\Delta H = 0,q = 9.1\text{ }kJ$
B.$w = 9.1\text{ }J,\Delta U = 9.1\text{ }J,\Delta H = 0;q = 0$
C.$w = + 4.1\text{ }kJ,\Delta U = 0,\Delta H = 0;q = - 4.1\text{ }kJ$
D.$w = - 3.9\text{ }kJ,\Delta U = 0,\Delta H = 0;q = 3.9\text{ }kJ$

Solution

For isothermal reversible process $\Delta U = \Delta H = 0$

$${w_{\text{iso~}} = - p_{1}v_{1}ln\frac{P_{1}}{P_{2}} }{w_{\text{iso~}} = - 0.5 \times 10^{6} \times 20 \times 10^{- 3}ln\frac{0.5}{0.2} }{w_{\text{iso~}} = - 0.5 \times 10^{6} \times 20 \times 10^{- 3} \times 2.303 \times (.6989 - .3010) }{w \simeq - 9.1\text{ }kJ }{q = - w = 9.1\text{ }kJ}$$

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