ElectrochemistryHard
Question
In a conductivity cell, the two platinum electrodes, each of area 10 cm2 are fixed 1.5 cm apart. The cell contained 0.05 N solution of a salt. If the two electrodes are just half dipped into the solution which has a resistance of 50 Ω, the equivalent conductance of the salt solution, in Ω−1 cm2 eq−1, is
Options
A.120
B.60
C.240
D.3000
Solution
Conductivity of solution will remain uncharged but the cell constant becomes double.
$\kappa = G \times G^{*} = \frac{1}{50} \times \frac{1.5}{5} = \frac{3}{5} \times 10^{- 2}\text{ oh}\text{m}^{- 1}\text{ c}\text{m}^{- 1} $$$\therefore\Lambda_{eq} = \frac{K}{C} = \frac{\frac{3}{5} \times 10^{- 2}}{0.05 \times 10^{- 3}} = 120\text{ oh}\text{m}^{- 1}\text{ c}\text{m}^{2}\text{ e}\text{q}^{- 1}$$
Create a free account to view solution
View Solution FreeMore Electrochemistry Questions
Using the standard potential values given below, decide which of the statements I, II, III, IV are correct. Choose the r...A cell contains two hydrogen electrodes. The negative electrode is in contact with a solution of 10−6 M hydrogen ions. T...Given below are the half-cell reactions Mn2+ + 2e- → Mn ; Eo = - 1.18 V (Mn3+ + e- → Mn2+) ; Eo = + 1.51 V T...A student made the following observations in the laboratory:(I) Clean copper metal did not react with 1 M – Pb(NO3)2 sol...Which of the following curve represents the variation of λM with √C for AgNO3 ?...