Question
Given below are two statements:
Statement I: The number of species among ${SF}_{4}$, ${NH}_{4}^{+},\ \left\lbrack {NiCl}_{4} \right\rbrack,\ {XeF}_{4},\ \left\lbrack {PtCl}_{4} \right\rbrack^{2 -},\ {SeF}_{4}\ $ and $\left\lbrack Ni(CN)_{4} \right\rbrack^{2 -}$, that have tetrahedral geometry is 3 .
Statement II: In the set $\left\lbrack {NO}_{2},{BeH}_{2},{BF}_{3},{AIC1}_{3} \right\rbrack$, all the molecules have incomplete octet around central atom. In the light of the above statements, choose the correct answer from the options given below:
Options
Solution
Statement-I
${SF}_{4}$ (See-saw)
${XeF}_{4}$ (square planar),
$\left\lbrack {PtCl}_{4} \right\rbrack^{2 -}$ (square planar),
[ $\left. \ {NiCl}_{4} \right\rbrack^{2 -}$ (Tetrahedral),
$\left\lbrack Ni(CN)_{4} \right\rbrack^{2 -}$ (square planar),
${SeF}_{4}$ (See-saw)
${NH}_{4}^{+}$(Tetrahedral)
Statement-II
${NO}_{2}$ (seven electrons on N )
${BeH}_{2}$ (four electrons on Be )
${BF}_{3}$ (six electrons on B )
${AlCl}_{3}$ (six electrons on Al )
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