Chemical BondingHard

Question

Given below are two statements:

Statement I: The number of pairs among [ ${SiO}_{2},{CO}_{2}$ ], $\left\lbrack SnO,{SnO}_{2} \right\rbrack,\left\lbrack PbO,{PbO}_{2} \right\rbrack$ and $\left\lbrack GeO,{GeO}_{2} \right\rbrack$, which contain oxides that are both amphoteric is 2 .

Statement II : ${BF}_{3}$ is an electron deficient molecule can act as a lewis acid, forms adduct with ${NH}_{3}$ and has a trigonal planar geometry.

In the light of the above statement, choose the correct answer from the option given below.

Options

A.Both Statement I and Statement II are true.
B.Both Statement I and Statement II are false.
C.Statement I is true but Statement II is false.
D.Statement I is false Statement II is true.

Solution

$\Rightarrow {SiO}_{2},{CO}_{2},GeO,{GeO}_{2}$ are acidic in nature. $SnO,{SnO}_{2},PbO,{PbO}_{2}$ are amphoteric in nature.

$\Rightarrow {BF}_{3}$ is lewis acid acoording to lewic octet theory and has ${sp}^{2}$ hybridization with trigonal planar geometry and it can accept lone pair form ammonia to form adduct.

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