Nitrogen Containing CompoundHard

Question

The compound which give an oily nitrosoamine on reaction with acid at low temperature, is

Options

A.CH3NH2
B.(CH3)2CHNH2
C.CH3 - NH - CH3
D.(CH3)3N

Solution

Out of primary, secondary and tertiary amines, the secondary amines, on reaction with HNO2 produce yellow oily conpoundscalled nitro amines.
CH3 - NH - CH2 + NHO2 → CH2 CH3 + H2O
        (2o amine)              Dimethyl nitrosoamine (oily)

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