ThermochemistryHard

Question

The heat of combustion of yellow phosphorous is - 9.91 kJ and of red phosphorous to redphosphorus is :

Options

A.- 9.91 kJ
B.- 8.78 kJ
C.- 9.34 kJ
D.- 1.13 kJ

Solution

P(red) + O2 → P2O5 ; H = - 8.78
P(yellow) + O2 → P2O5 ; = - 9.91
Subtracting
P(red) + O2 - P(Yellow) = 0;
ᐃH = - 8.78 + 9.91 = 3.113
P(Red) → P(Yellow)       ᐃH  =  1.13
P(Yellow) → P(Red)       ᐃH = - 1.13

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